I don't see that there is a simple answer of mains fans being better (or not) than 12 volt fans, since several factors have to to taken into consideration;
a) Power consumption. Which uses the most electricity? The 80mm mains fan uses 13w at 85ma and the 120mm mains fan uses 22w at 140ma, but how much power does a 12volt PC fan running off, say, a 300w PC power supply use?. Or even, how much power does several 12volt fans use when running off the same PC power supply? And I'm sure the answer isn't 300w. How much power does a PC power supply use to provide a 12volt supply?

Capacity. The 80mm mains fan moves 28cfm and the 120mm mains fan moves 80cfm, but how much does one PC fan move? or how much does several move when connected to the same PC power supply?
c) Noise. How noisy are the mains fans? Some PC power supplies can be noisy even without powering 12volt fans or anything else.
d) Space saving. Using a PC power supply in a small space, like a PC case, means that a lot of space is taken up by the power supply. Sorry for stating the obvious, but a mains fan can be wired straight to the mains, without the need for a bulky power supply. I'm collecting ideas and materials for converting a PC case, and as much as I like converting PC power supplies, I don't think I'll be using one. If you need a 12volt PSU, look at the compact fanless ones used by some smaller printers, freeview boxes and older TFT monitors.
e) Cost. As been said by others, these mains fans are expensive. Look out for old servers etc. Don't ever pay for these type of fans, there is always some old equipment lying around.
f) Simplicity. Working with electricity doesn't suit everybody. It is easier to wire a mains fan to a bit of mains cable and a plug, than it is to modify a PC power supply to give a 12volt supply.
Thanks to everybody for making me considering using fans rather than 12 volt fans.